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1、that既可指人又可指物,而which则一般指物.区别如下：一、以下情况不能用that,只能用which：在非限定性定语从句中,逗号之后不能用that；2、介词后面不能用that.3、当主句中的主语被that修饰时。

2、That cat which I found in the street belongs to Jane.二、以下情况不能用which,只能用that：前面的先行词是不定代词时,如 all ,anything ,nothing,the one 等；2、如果先行词出现了the only ,the very 时；This is the very book that I lost yesterday.3、如果先行词出现了序数词和形容词最高级时；4、如果先行词中既有人又有物时,如：They are talking about the school and the teachers that they visited yesterday.5、在there be句型中,只用that6、如有两个定语从句,其中一个已用which引导,另一个宜用that .Johnson built up a factory which produced things that had never been seen before.7、主句是以which或who开头的特殊疑问句时Who is the woman that was praised at the meeting.8、当先行词在从句和主句中都作表语时,无论先行词是人还是物。

3、9、当先行词被all, any, some, no, not, every, each等修饰时。

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